Self-adaptive microcapsule for packaging dust suppressant calcium alginate, preparation method of self-adaptive microcapsule and bio-based dust suppression material

A calcium alginate, bio-based technology, used in chemical instruments and methods, other chemical processes, etc., can solve problems such as corrosiveness, unfavorable cost, and toxicity

Pending Publication Date: 2021-11-02
SHANDONG UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (1) Although there are many types of existing chemical dust suppressants, there are some common problems, such as single function, high price, and even a series of disadvantages such as toxicity, corrosion, refractory degradation and secondary pollution, etc. application limited
In the actual application process, the conventional dust suppressant plays the role of moisture absorption and water retention in the early stage, but the action time is short, which is not conducive to cost control
[0007] (2) Although slow-release microcapsules have been applied in many fields, they still belong to a technical gap in coal mine dust control
[0008] (3) The reagents used in the preparation process of similar products are poisonous and harmful, which will cause secondary pollution to the environment and pose a certain threat to human life and health
[0009] (4) About one million tons of peanut shells are produced in China every year, but most of them are discarded or burned, resulting in a huge waste of resources

Method used

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  • Self-adaptive microcapsule for packaging dust suppressant calcium alginate, preparation method of self-adaptive microcapsule and bio-based dust suppression material
  • Self-adaptive microcapsule for packaging dust suppressant calcium alginate, preparation method of self-adaptive microcapsule and bio-based dust suppression material
  • Self-adaptive microcapsule for packaging dust suppressant calcium alginate, preparation method of self-adaptive microcapsule and bio-based dust suppression material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Cellulose nanofibrils are extracted from peanut shells. The extraction method of extracting cellulose nanofibrils from peanut shells is:

[0054] Accurately weigh 10 g of dried peanut shell powder, place it in a Soxhlet extractor, use benzene-ethanol solution (2:1 by volume) to soak at 90°C for 6 hours, remove the extract, and dry it. The dried samples were soaked in sodium chlorite solution at 75°C for 1 hour under acidic conditions (pH=4-5, adjusted by glacial acetic acid), and repeated five times in succession to remove lignin to obtain cellulose sample S1 . Prepare 300ml of 5wt% potassium hydroxide solution, soak the sample in it at room temperature for 24 hours, remove hemicellulose, and obtain treated cellulose sample S2. Finally, in order to further remove residual lignin, the sodium chlorite solution (what is the mass concentration) was soaked repeatedly for 2-3 times to obtain purified cellulose sample S3. In order to make peanut shell cellulose nanometer, i...

Embodiment 2

[0057] The core material of the dust-suppressing microcapsules consists of 1% dimethyl diallyl ammonium chloride (DMDAAC for short), 1% cellulose nanofibrils, 5% acrylic acid (AA for short), and 0.125% acrylic acid according to the mass fraction. The agent is composed of ammonium persulfate and potassium thiosulfate, 0.09% of cross-linking agent N,N'-methylenebisacrylamide, alkaline pH regulator sodium hydroxide, and the balance of water. Dimethyldiallyl ammonium chloride: cellulose nanofibrils: acrylic acid 1:1:5. Preparation of dust-suppressing microcapsule core material,

[0058] Accurately weigh dimethyl diallyl ammonium chloride, cellulose nanofibrils and acrylic acid in a container, add deionized water and stir until they dissolve.

[0059] Prepare sodium hydroxide solution, put it into the container under the condition of ice-water bath to neutralize acrylic acid to neutral, then add the initiator to it, stir and mix well, react at 55-60°C for 1 hour, and finally slowl...

Embodiment 3

[0067] The self-adaptive microcapsules of calcium alginate, an encapsulated dust suppressant, are made by mixing oil phase materials and water phase materials at a volume ratio of 1:5.

[0068] The water phase material is composed of 3% dust-suppressing microcapsule capsule core material, 12% sodium alginate, 7% nano-scale calcium chloride and water as the balance according to the mass percentage.

[0069] The dust-suppressing microcapsule capsule core material consists of 2.5% dimethyl diallyl ammonium chloride, 1% cellulose nanofibrils, 10% acrylic acid, 0.25% initiator ammonium persulfate, 0.18 % of cross-linking agent N, N'-methylenebisacrylamide, alkaline pH regulator sodium hydroxide, and the balance of water. The ratio of dimethyl diallyl ammonium chloride: cellulose nanofibrils: acrylic acid is 2.5:1:10, the crosslinking agent is N,N'-methylenebisacrylamide, and the initiator is potassium thiosulfate.

[0070] The oil phase is a liquid paraffin solution of Span-85 wit...

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Abstract

The invention provides a self-adaptive microcapsule for packaging dust suppressant calcium alginate, a preparation method of the self-adaptive microcapsule and a bio-based dust suppression material. The self-adaptive microcapsule is prepared from the following components in percentage by mass: 1%-2.5% of dimethyl diallyl ammonium chloride, 1%-2.5% of cellulose nanofibril, 5%-10% of acrylic acid, 0.125%-0.25% of an initiator, 0.09%-0.18% of a cross-linking agent and the balance of water. The self-adaptive microcapsule is adjusted to be neutral by using an alkaline pH regulator. The self-adaptive microcapsule can be used in cooperation with a conventional dust suppressant or the bio-based dust suppression material. The conventional dust suppressant or the bio-based dust suppression material plays a role in moisture absorption in the early stage, and the dust suppression microcapsule plays a role in water retention in the later stage. The dust suppression microcapsule and the dust suppressant or the bio-based dust suppression material perform respective functions, the water retention time of the dust suppressant is prolonged to the maximum extent, and synergistic dust suppression is achieved.

Description

technical field [0001] The invention belongs to the field of dust suppression in coal mines and the field of microcapsule technology, and in particular relates to a self-adaptive microcapsule of an encapsulated dust suppressant calcium alginate, a preparation method and a bio-based dust suppression material. Background technique [0002] The quality of the ecological environment plays a vital role in the survival and development of human beings and other organisms. A large amount of dust is produced during the production and operation of open-pit mines, known as the "invisible killer", and has become the main factor restricting the safety of coal mine production in recent years. The hazards of coal dust mainly include pneumoconiosis, environmental pollution, wearing equipment and coal dust explosion. According to incomplete statistics, in the past ten years, China has reported 272,000 cases of occupational diseases, including 212,000 cases of occupational pneumoconiosis, ac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/22
CPCC09K3/22
Inventor 周刚苗彦平张宏常波峰赵义元刘宽孙彪李帅龙孟群智徐乙鑫邢占一
Owner SHANDONG UNIV OF SCI & TECH
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