Method for predicting solubility of CO2 in NaCl aqueous solution based on CPA state equation
An equation of state and aqueous solution technology, which is applied in the field of predicting the solubility of CO2 in NaCl aqueous solution based on the CPA equation of state, can solve the problems of low accuracy and narrow temperature and pressure range, and achieve the effect of high accuracy, low initial value requirements and the best prediction effect.
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[0131] Below in conjunction with accompanying drawing, technical solution of the present invention will be introduced in detail:
[0132] In this implementation example, using the established CPA-SRK-WS model, the CO 2 Solubility in sodium chloride solution was calculated and compared with experimental data. The parameters of the CPA-SRK-WS model were optimally fitted in a large range of temperature and pressure using the least square method, as shown in Table 1. Table 3 lists the H obtained from the regression of experimental data 2 O-NaCl system and CO 2 - Interaction parameter (D) values for the NaCl system. For an overview of the calculation process, see figure 1 , first input temperature T, pressure P and composition parameter z i ; Then calculate the contrast temperature T according to the contrast state principle r , Contrast pressure P r , and use the Wilson formula to estimate the equilibrium constant (K i ) initial value; with K i Enter the material balanc...
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