A kind of graphene plant fiber nanocomposite oil-absorbing agent and preparation method thereof
A plant fiber and nanocomposite technology, applied in separation methods, chemical instruments and methods, other chemical processes, etc., can solve the problems of poor comprehensive performance, narrow application area of in-situ combustion, energy waste, etc., and achieve excellent oil-water separation performance. , good oil-water separation performance, and promote the effect of compounding and synergy
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Embodiment 1
[0039] (1) Add 3.5 parts of natural flake graphite and 2 parts of sodium nitrate to a reaction kettle with a stirring device and a thermometer, then add 120 parts of concentrated sulfuric acid, and keep the temperature of the ice-water bath at 0°C, slowly add 24 parts of high Potassium manganate; after 1 hour, heat up to 35°C, react for 16h, then add 475 parts of water, and continue to heat up to 65°C, after 0.5h of reaction, add hydrogen peroxide dropwise until no bubbles are generated in the reaction solution, use 10% carbonic acid Wash with sodium hydrogen and deionized water until the pH value is 7 and no sulfate ions are detected, then fully dry at 60°C to obtain graphite oxide;
[0040] (2) Place the prepared graphite oxide in 100 parts of deionized water, and perform ultrasonic stripping for 2.5 hours to obtain a stable graphene oxide dispersion; move the dispersion into a reaction kettle, heat up to 90°C while stirring, and then add dropwise 5 parts of hydrazine hydrat...
Embodiment 2
[0048] (1) Add 3 parts of natural flake graphite and 1.8 parts of sodium nitrate to a reaction kettle with a stirring device and a thermometer, then add 120 parts of concentrated sulfuric acid, and keep the temperature of the ice-water bath at 0°C, slowly add 24 parts of high Potassium manganate; after 1 hour, heat up to 35°C, react for 16h, then add 475 parts of water, and continue to heat up to 65°C, after 0.5h of reaction, add hydrogen peroxide dropwise until no bubbles are generated in the reaction solution, use 10% carbonic acid Wash with sodium hydrogen and deionized water until the pH value is 7 and no sulfate ions are detected, then fully dry at 60°C to obtain graphite oxide;
[0049] (2) Place the prepared graphite oxide in 100 parts of deionized water, and perform ultrasonic stripping for 2.5 hours to obtain a stable graphene oxide dispersion; move the dispersion into a reaction kettle, heat up to 90°C while stirring, and then add dropwise 5 parts of hydrazine hydrat...
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