a c-based 3 Luminescent liquid crystal material with symmetrical structure and preparation method thereof
A technology of liquid crystal materials and symmetry, which is applied in the preparation of luminescent materials, liquid crystal materials, and carbon-based compounds. It can solve the problems that luminescent liquid crystal materials cannot have both liquid crystallinity and AIE/AIEE effects, and achieve increased brightness and simplified device structure. , easy-to-achieve effects
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Embodiment 1
[0050] (1) Ar is The preparation of intermediate 1, its preparation route is The specific preparation steps are: take a 50mL two-necked flask, put it into a magnet, add 2.0g (9.65mmol) of reactant X1, start stirring, carry out vacuuming and blowing nitrogen for 3 times, dissolve it with 20mL chloroform, and put it in an ice bath. , slowly added 2.56mL (28.95mmol) of trifluoromethanesulfonic acid with a constant pressure funnel, stirred for 1h; continued to stir after returning to room temperature, then heated to reflux for 12h, and monitored the progress of the reaction with a TLC plate; 3 Saturated solution quenched trifluoromethanesulfonic acid, then the mixture was filtered, and the resulting solid was washed 3 times with n-hexane, water, and dichloromethane respectively to obtain a yellow-brown powder (collect the filtrate and washing liquid, and the resulting organic layer was washed with dichloromethane After extraction, it was collected by spin-drying, most of which ...
Embodiment 2
[0055] (1) Prepare a luminescent liquid crystal material with the intermediate 1 (Y1-1) and intermediate 2 (Y2-1) obtained in Example 1 as substrates. The specific preparation steps are: in a 100mL single-necked flask, put a magnet, Add 186mg (0.30mmol) of intermediate 1 (Y1-1), 566mg (1.08mmol) of intermediate 2 (Y2-1), inject 40mL of absolute ethanol (EtOH), and 15mL of tetrahydrofuran (THF) to promote the dissolution of the reactant; room temperature conditions Stir under the pressure, then weigh 0.35 g of NaOH solid, slowly add it to the flask several times, then cover the stopper, and tie the needle of the syringe to keep the air pressure balance; use the TLC plate to monitor the progress of the reaction, and add 10wt% NaOH after the reaction is completed. dilute hydrochloric acid to adjust the pH value, and use pH test paper to detect that it is neutral; then spin the solvent dry, add an appropriate amount of chloroform to dissolve it ultrasonically, transfer it to a sepa...
Embodiment 3
[0060] (1) Prepare the luminescent liquid crystal material with the intermediate 1 (Y1-1) and intermediate 2 (Y2-2) obtained in the embodiment as the substrate, the specific preparation steps are the same as the Z-1-1 in the embodiment 2, and the obtained The luminescent liquid crystal material is a yellow solid with a yield of 28%. The luminescent liquid crystal material obtained in this example is named Z1-2. The structural characterization data of Z1-2 is 1 H NMR (400MHz, Chloroform-d) δ7.90(dd, J=14.4, 8.1Hz, 12H), 7.66(dd, J=24.1, 8.3Hz, 18H), 7.43(s, 3H), 7.02(s, 6H),6.61(s,6H),4.97(s,6H),3.95(s,18H),1.77(s,24H),1.45(s,124H),0.86(s,27H). 13 C NMR(100MHz,Chloroform-d)δ153.5,139.4,131.5,129.8,128.2,127.7,127.5,127.3,115.5,111.6,106.2,73.6,70.7,69.3,32.1,30.5,29.7,29.8,23,228.6 , 14.3.
[0061] (2) the liquid crystallinity of Z1-2 that this embodiment makes is tested: the TGA result of Z1-2 is as follows Figure 5a As shown, when the temperature reaches 327°C, the sampl...
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