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Fischer-Tropsch slurry bed reaction system and Fischer-Tropsch synthesis reaction method

A reaction system, Fischer-Tropsch synthesis technology, applied in chemical instruments and methods, preparation of liquid hydrocarbon mixtures, petroleum industry, etc., can solve the problems of catalyst overheating, deposition, catalyst deactivation, etc. The effect of heat exchange efficiency and safety improvement

Inactive Publication Date: 2018-03-13
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0003] In addition, local overheating of the catalyst often occurs in the Fischer-Tropsch synthesis reaction, which causes carbon deposition on the catalyst and even deposits in the reactor, resulting in rapid deactivation of the catalyst and a decrease in the yield of the target product, etc.

Method used

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  • Fischer-Tropsch slurry bed reaction system and Fischer-Tropsch synthesis reaction method

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Embodiment 1

[0055] This example is used to illustrate the Fischer-Tropsch slurry bed reaction system and the Fischer-Tropsch synthesis reaction method of the present invention.

[0056] use figure 1 In the Fischer-Tropsch slurry bed reaction system shown, the syngas is introduced from the lower part of the slurry bed reactor 1, and the heater 7 is set so that the temperature rise rate of the flowing water is 20°C / h; When the temperature in 1 reaches 120°C, set the heater 7 so that the temperature rise rate of the water flowing through is 10°C / h; when the temperature in the slurry bed reactor 1 reaches 200°C, set the heater 7 so that the flow rate The heating rate is 5°C / h; when the temperature in the slurry bed reactor 1 reaches 250°C, it is deemed to have reached the specified reaction temperature of the Fischer-Tropsch synthesis reaction, and the heater 7 is turned off to stop heating; wherein, the steam drum 5 is set The threshold value of the pressure control valve 9 is 4MPa; the sup...

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Abstract

The invention relates to the field of Fischer-Tropsch synthesis, and discloses a Fischer-Tropsch synthesis slurry bed reaction system and a Fischer-Tropsch synthesis reaction method. The slurry bed reaction system comprises a slurry bed reactor, a heat exchanger, an external heat exchange device and a part for supplementing cooling water; the heat exchanger is arranged inside the slurry bed reactor; the external heat exchange device is arranged outside the slurry bed reactor; the external heat exchange device comprises a steam pocket, a buffer tank and a heater which are sequentially connectedin series; the heater communicates with a lower water inlet of the heat exchanger; the steam pocket communicates with an upper water outlet of the heat exchanger; and the part for supplementing the cooling water is used for providing the cooling water to the external heat exchange device. The system can timely and effectively remove excessive heat brought by temperature runaway when the local temperature runaway of the catalyst is generated, so that the yield of a target product is ensured, and the operation safety of a device is improved.

Description

technical field [0001] The invention relates to the field of Fischer-Tropsch synthesis, in particular to a Fischer-Tropsch slurry bed reaction system and a method for Fischer-Tropsch synthesis. Background technique [0002] The Fischer-Tropsch synthesis reaction is a strongly exothermic reaction. The distribution of Fischer-Tropsch synthesis products and the activity of catalysts are very sensitive to temperature. Maintaining a relatively constant temperature in the reactor is very important for the smooth progress and safe operation of the reaction in the slurry bed reactor. Therefore, when performing the Fischer-Tropsch synthesis reaction, it is necessary to remove the heat of reaction in the slurry bed reactor out of the reactor evenly and quickly. [0003] In addition, local overheating of the catalyst often occurs in the Fischer-Tropsch synthesis reaction, which causes carbon deposition on the catalyst and even deposits in the reactor, resulting in rapid deactivation o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J8/22C10G2/00
CPCB01J8/22B01J2208/00106C10G2/34
Inventor 杜冰卜亿峰刘潇姚德良苗强孙永伟
Owner CHNA ENERGY INVESTMENT CORP LTD
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