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Photosensitizers and Photoelectric Conversion Elements

A technology for photoelectric conversion elements and photosensitizers, applied in the fields of photosensitizers and photoelectric conversion elements, can solve the problems that conversion efficiency and durability have not yet reached a practical level, and achieve improved photoelectric conversion efficiency, improved adsorption stability, and high molar absorption coefficient. Effect

Active Publication Date: 2018-06-08
CHEMICREA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to overcome this situation, the development of metal-free (metal free) organic pigments is in vogue in the world, but the current situation is that the conversion efficiency and durability have not yet reached a practical level (for example, Patent Document 2).

Method used

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  • Photosensitizers and Photoelectric Conversion Elements
  • Photosensitizers and Photoelectric Conversion Elements
  • Photosensitizers and Photoelectric Conversion Elements

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0166]

[0167] Aldehyde (B-01) (0.88 g) and intermediate (C-01) (0.50 g) were dissolved in acetic acid (10 mL), and heated and stirred at 100° C. for 4 hours. The reaction mixture was cooled to room temperature and solidified. The crude crystals were separated by filtration, and were separated by column chromatography (silica gel, developer: CHCl 3 / MeOH=100 / 1) was separated and purified, whereby 0.85 g of a pigment (I-03) was obtained as a brown solid (69% yield). λmax=545nm (CHCl 3 ).

[0168] The structure of the obtained pigment (I-03) was identified by NMR analysis.

[0169] 1 H NMR (400MHz, DMSO-d 6 )

[0170] δ (ppm) = 13.65 (1H, br.s), 8.67 (1H, br.s), 8.33 (1H, dd, J = 8.0, 7.6Hz), 8.24 (1H, d, J = 11.6Hz), 8.20 (1H,br.s),7.94(1H,dd,J=7.6,7.6Hz),7.65(1H,s),7.41-7.49(3H,m),7.30-7.38(5H,m),7.19-7.23 (4H,m),7.11(1H,s),7.07(2H,d,J=8.4Hz),6.87(1H,d,J=8.8Hz),5.07-5.11(1H,m),3.82-3.87( 1H,m),2.03-2.12(1H,m),1.69-1.83(2H,m),1.59-1.67(2H,m),1.27-1.38(1H,m)

Embodiment 2

[0171]

[0172] Using the same method as in Example 1, and using an aldehyde intermediate (B-02), a pigment (I-05) was obtained as a black solid. λmax=541nm (CHCl 3 ).

[0173] The structure of the obtained pigment (I-05) was identified by NMR analysis.

[0174] 1 H NMR (400MHz, DMSO-d 6 )

[0175] δ(ppm)=13.63(1H,br.s),8.72(1H,br.s),8.35(1H,d,J=8.0Hz),8.28(1H,br.s),8.25(1H,d, J=11.6Hz),7.95(1H,dd,J=8.0,7.6Hz),7.90(1H,d,J=8.4Hz),7.83(1H,d,J=7.2Hz),7.69(1H,s) ,7.67(1H,d,J=1.6Hz),7.56(1H,d,J=7.2Hz),7.41(1H,dd,J=8.0,1.2Hz),7.36(1H,dd,J=8.0,7.2 Hz), 7.32(1H,dd,J=8.4,7.2Hz),6.87(1H,d,J=8.4Hz),5.24-5.27(1H,m),3.90-3.94(1H,m),2.08-2.18 (1H,m),1.74-1.88(3H,m),1.64-1.73(1H,m),1.50(3H,s),1.47(3H,s),1.37-1.53(1H,m)

Embodiment 3

[0176]

[0177] Using the same method as in Example 1, and using an aldehyde intermediate (B-03), a pigment (I-06) was obtained as a black solid. λmax=546nm (CHCl 3 ).

[0178] The structure of the obtained pigment (I-06) was identified by NMR analysis.

[0179] 1 H NMR (400MHz, DMSO-d 6 )

[0180] δ (ppm) = 13.07 (1H, br.s), 8.17 (1H, br.s), 7.81 (1H, dd, J = 7.6, 7.2Hz), 7.73 (2H, d, J = 9.6Hz), 7.41 (1H,d,J=8.0Hz),7.34(1H,d,J=8.4Hz),7.27(1H,d,J=7.2Hz),7.14(1H,s),6.99(1H,s),6.92 (1H,d,J=6.8Hz),6.88(1H,d,J=8.0Hz),6.83(1H,dd,J=7.2,6.0Hz),6.80(1H,dd,J=7.2,6.4Hz) ,6.30(1H,d,J=8.4Hz),4.72-4.75(1H,m),3.36-3.40(1H,m),1.57-1.65(1H,m),1.43-1.56(4H,m),1.28 -1.35(1H,m),1.11-1.26(3H,m),0.84-0.95(1H,m),0.45-0.59(4H,m),0.16(3H,t,J=7.2Hz),0.10(3H ,t,J=7.2Hz),0.02-0.04(4H,m)

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Abstract

The present invention provides a photosensitizer excellent in conversion efficiency and durability. The photosensitizer of the present invention is characterized in that it is a dye represented by the following formula or a salt thereof. In addition, in the following chemical formulae, m is an integer of 0-4. n is an integer of 0 or 1. p is an integer of 0-2. R1, R2, R3 represent hydrogen atoms, alkyl or aryl groups, etc., R4, R4', R4", R5, R6, R7, R8, R9 represent hydrogen atoms, alkyl groups, etc. X is carbonyl, etc. Z1, Z2 represents Carboxyl etc.

Description

technical field [0001] The present invention relates to a photosensitizer and a photoelectric conversion element using the photosensitizer. Background technique [0002] Among organic solar cells attracting attention as next-generation solar cells in recent years, there are broadly divided into organic thin-film type and dye-sensitized type. Organic thin-film solar cells combine organic materials to make p-n junctions and utilize them. The working mechanism is exactly the same as that of inorganic solar cells represented by silicon. In contrast, dye-sensitized solar cells (Dye Sensitized Solar Cells, DSCs) are characterized by the use of modified electrodes that combine organic dyes as photosensitizers with inorganic semiconductors such as titanium oxide and zinc oxide. , In addition, the working mechanism of dye-sensitized solar cells is completely different from that of inorganic solar cells, rather close to photosynthesis. This solar cell, which should be called an inor...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/20C09B23/00H10K99/00
CPCH01G9/20C09B23/0066C09B23/04C09B23/06C09B23/083C09B23/0075Y02E10/542H01G9/2059C09B23/00Y02E10/549H10K85/615H10K85/656H10K85/657H10K85/6572H10K30/151
Inventor 三浦伟俊楮山真吾井上由纪子东岛伸治
Owner CHEMICREA
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