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Bithiophene pyrrolic compound containing diphenyl-4-phenylamine diphenyl diamine and preparation as well as polymer and preparation method and application

An aniline biphenyl diamine group and bisthieno technology, which is applied to the bis thienopyrrole compound containing diphenyl-4-aniline biphenyl diamine group and the preparation and polymer and preparation and application fields, can solve the problem of discoloration Single, electrochromic polymer film-forming problems, etc., to achieve the effect of good electrochromic performance and film-forming performance

Inactive Publication Date: 2015-12-09
HEILONGJIANG UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to solve the problems of poor film-forming properties and single discoloration of existing electrochromic polymers, and provide bis-thienopyrrole compounds containing diphenyl-4-aniline biphenyl diamine groups and their preparation and polymerization Objects and preparation methods and applications

Method used

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  • Bithiophene pyrrolic compound containing diphenyl-4-phenylamine diphenyl diamine and preparation as well as polymer and preparation method and application
  • Bithiophene pyrrolic compound containing diphenyl-4-phenylamine diphenyl diamine and preparation as well as polymer and preparation method and application
  • Bithiophene pyrrolic compound containing diphenyl-4-phenylamine diphenyl diamine and preparation as well as polymer and preparation method and application

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specific Embodiment approach 1

[0057] Specific embodiment one: In this embodiment, the structural formula of the bisthienopyrrole compound containing diphenyl-4-anilinebiphenylenediamine group is:

[0058]

specific Embodiment approach 2

[0059] Specific embodiment two: this embodiment is the preparation method of bisthienopyrrole compound containing diphenyl-4-aniline biphenyl diamine group is prepared according to the following method:

[0060] 1. Synthesis of 2,5-bis(2-thiophene)-1,4-butanedione monomer:

[0061] 1. Aluminum trichloride is dispersed in anhydrous dichloromethane to obtain a suspension of aluminum trichloride and anhydrous dichloromethane;

[0062] The volume ratio of the amount of aluminum trichloride described in step 1. to anhydrous dichloromethane is (0.06mol~0.1mol): 30mL;

[0063] 2. Add the mixed solution of thiophene and succinoyl chloride / dichloromethane dropwise to the suspension of aluminum trichloride and anhydrous dichloromethane obtained in step 1. respectively at a rate of 20 drops / min to 30 drops / min. In the turbid liquid, stir and react at a stirring speed of 600r / min to 700r / min for 7h to 9h, then add ice and hydrochloric acid with a mass fraction of 35% to 37%, and then sti...

specific Embodiment approach 3

[0088]Specific embodiment three: the difference between this embodiment and specific embodiment two is: the 2,5-bis(2-thiophene)-1,4-butanedione monomer described in step three and N,N'- The molar ratio of diphenyl-N,N'-bis(4-phenylamine)benzidinediamine is 0.002:0.001. Others are the same as in the second embodiment.

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Abstract

The invention provides a bithiophene pyrrolic compound containing diphenyl-4-phenylamine diphenyl diamine and preparation as well as a polymer and a preparation method and application, and relates to a thienyl pyrrolic compound and a preparation as well as the polymer prepared by utilizing the thienyl pyrrolic compound and the preparation method and the application of the polymer. The invention aims at solving the problem that a current existing electrochromic polymer is poor in film-forming property and single in color change. The structural formula of the compound is shown in the specification, and the method of the compound comprises the step of adding 2,5-bi(2-thiophene)-1,4-butanedione monomer, N,N'-diphenyl-N,N'-bi(4-phenylamine) diphenyl diamine and p-toluenesulfonic acid into methylbenzene for reaction, so as to obtain the compound. The structural formula of the polymer is shown in the specification, and the polymer is obtained by performing polymerization on the compound. The bithiophene pyrrolic compound containing the diphenyl-4-phenylamine diphenyl diamine is applied in an electrochromic material, a photoelectronic device or a biosensor. The invention can obtain the bithiophene pyrrolic polymer containing the diphenyl-4-phenylamine diphenyl diamine.

Description

technical field [0001] The invention relates to a thienylpyrrole compound, a preparation method, a polymer prepared by using the same, a preparation method and an application of the polymer. Background technique [0002] The real start to study the electrochemical properties of thienopyrrole derivatives began in 2000. Enric Brillas et al. studied the electrochemical behavior of 2,5-dithienylpyrrole on a Pt electrode; Chane-Ching, L.Toppare and A.Cihaner etc. began to synthesize a large number of new thienopyrrole derivatives, and studied their photoelectrochemical properties in detail. [0003] At present, a large number of polythiophene and polypyrrole derivatives reported in the literature are obtained by chemical oxidation or electrochemical oxidation. However, while oxidizing thiophene and pyrrole monomers, it will lead to peroxidation of the polymer itself, although it can be To prevent this phenomenon by lowering the oxidation potential or strictly controlling the amo...

Claims

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Application Information

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IPC IPC(8): C07D409/14C08G61/12C09K9/02
CPCC07D409/14C08G61/126C08G2261/11C08G2261/18C08G2261/228C08G2261/3229C08G2261/354C08G2261/44C08G2261/54C09K9/02C09K2211/1458C09K2211/1466
Inventor 牛海军蔡姝崴蒲丽莉郑冰
Owner HEILONGJIANG UNIV
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