Paste composition and roasted article pattern
A technology of composition and fired products, which is applied in the direction of photolithography, optics, and optomechanical equipment on the patterned surface. It can solve the problems of increased viscosity of the paste composition and easy generation of development residues in the coating film, and achieve long-term stability. Preservation, suppression of viscosity increase, and excellent dispersibility
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[0064] Hereinafter, examples and comparative examples are shown to specifically describe the present invention. Of course, the present invention is not limited to the following examples. In addition, "parts" and "%" are quality standards without special description.
[0065] The various additives shown in Table 1, the organic binder obtained in the following synthesis example, and the glass paste obtained in the following production example were used to paste and evaluate.
[0066] Table 1
[0067] Types of additives
Synthetic example
[0068] Synthesis example: (Synthesis of organic binder)
[0069] Add diethylene glycol monoethyl ether acetate as a solvent and azobisisobutyronitrile as a catalyst to a flask equipped with a thermometer, a stirrer, a dropping funnel, and a reflux condenser, and heat to 80 under a nitrogen atmosphere. ℃, the monomer of methacrylic acid and methyl methacrylate was mixed in the molar ratio of methacrylic acid: 0.4 mol, methyl methacrylate: 0.6 mol, and the monomer was added dropwise over about 2 hours, and then stirred for 1 hour After that, the temperature was increased to 115°C to inactivate it, and a resin solution was obtained. After cooling the resin solution, using tetrabutylammonium bromide as a catalyst, add butyl glycidyl ether: 0.4 mol and the same amount of carboxyl groups of the resulting resin at 95-115°C for 30 hours. Into the reaction, cooling. Furthermore, under the conditions of 95-105°C for 8 hours, the OH group of the obtained resin was subjected to an addition...
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