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Method for the determination of the conjugated diolefins content of a sample using near infrared spectrum and method for controlling a unit

A sample, spectroscopic technique used in gasoline containing sulfur, alkenes and diolefins to solve problems such as automation of the method

Active Publication Date: 2007-07-04
INST FR DU PETROLE
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  • Abstract
  • Description
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Problems solved by technology

However, due to the operations required for the analysis, such as liquid extraction or product transfer, the automation of the method is not considered, so that the method becomes a control method for continuous control of selected hydrogenation industrial units

Method used

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  • Method for the determination of the conjugated diolefins content of a sample using near infrared spectrum and method for controlling a unit

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Embodiment Construction

[0031] The description below refers to MAV, but the invention is applicable to all chemical methods for determining the diolefin content in cracked gasoline.

[0032] MAV is a measure of the presence of conjugated diolefins in gasoline based on the stoichiometric addition of diolefins to maleic anhydride. The method is expressed as several milligrams of maleic anhydride to one milligram of sample.

[0033] The method described in the present invention is to determine catalytic cracking gasoline or pyrolysis gasoline or coker gasoline or all of them according to the spectrum obtained in the near infrared (PIR) of the gasoline or the mixture, that is, the near infrared with a wavelength of 800-2500 nanometers. The MAV method for any blend of gasoline described above.

[0034] The method of deriving MAV by means of spectral PIR utilizes the comparison value between the spectrum of the sample under study and the spectra of all elements forming the so-called calibration matrix acc...

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Abstract

This invention describes a method for determining the content of conjugated diolefins by means of the measurement of the MAV of a sample of catalytic cracking gasoline or thermal cracking gasoline, from its NIR (near-infrared) spectrum, and the application of said method for monitoring a unit for selective hydrogenation of the cracking gasolines.

Description

technical field [0001] The present invention relates to a method for determining the different properties of hydrocarbon fractions, especially gasoline, especially catalytically cracked gasoline, evaporatively cracked gasoline, coker gasoline and their mixtures, based on their spectra obtained in the near infrared (abbreviated to spectrum PIR). methods with different properties. In general, the invention is useful for gasolines containing sulfur (10-10000 ppm), olefins (at least 5% by weight) and diolefins. The final distillation temperature of these gasolines should be below 300°C, preferably below 250°C. Background technique [0002] The wavelength corresponding to the near-infrared range is about 800-2500 nanometers (14286-4000cm -1 ). The properties determined by gasoline spectral PIR are very different, so far these properties are mainly density, octane number (RON and MON), vapor pressure Reid (RVP), ASTM distillation and chemical group (paraffin, aromatic, naphthen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G45/72C10G49/26G01N21/35
CPCG01N33/28G01N21/359G01N21/274G01N21/3563G01N2201/129
Inventor F·皮卡德C·洛帕茨加西阿J·-M·巴德F·瓦哈尔
Owner INST FR DU PETROLE
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