Boron-containing organic light emission diode device and preparation method thereof

Abstract

The present invention relates to an organic light emission diode device (OLED) structure, especially to a high-efficiency organic light emission diode device of a B-containing compound. The organic light emission diode device structure comprises an anode, a cavity injection/transmission layer, a luminescent layer, an electron injection/transmission layer and a cathode, wherein the luminescent layer comprises main body materials and doped materials; the main body materials are formed by signal materials and are also formed by mixing materials with different structures; and the doped materials are organic compounds containing boron, the energy level difference of the singlet state and the triplet state is not larger than 0.2ev, and the energy level of the singlet state and the energy level of the triplet state of the of the main body materials are both higher than that of the doped materials to prevent energy from passback and avoid reduction of the device luminescence efficiency. The present invention further provides a preparation method of the organic light emission diode device. The preparation method is utilized to obtain the organic light emission diode device which is high in efficiency, long in life and high in purity.

Description

technical field [0001] The invention relates to the technical field of semiconductors, in particular to the application of a boron-containing organic compound as a light-emitting layer doping material on an organic light-emitting diode and a device preparation method. Background technique [0002] Organic electroluminescent (OLED: Organic Light Emission Diodes) device technology can be used to manufacture new display products and also can be used to make new lighting products, which is expected to replace the existing liquid crystal display and fluorescent lighting, and has a wide application prospect. The OLED light-emitting device is like a sandwich structure, including electrode material film layers, and organic functional materials sandwiched between different electrode film layers. Various functional materials are superimposed on each other according to the application to form an OLED light-emitting device. As a current device, when a voltage is applied to the electrode...

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Problems solved by technology

[0004] Although theoretically TADF materials can achieve 100% exciton utilization, there are actually the following problems: (1) The T1 and S1 states of the designed molecules have strong CT characteristics, and the very small S1-T1 state energy gap, although it can A high T1→S1 state exciton conversion rate is achieved through the TADF process, but at the same time it leads to

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