Method for preparing mesoporous ts-1 titanium-silicon molecular sieve by hydrothermal crystallization
A titanium-silicon molecular sieve and hydrothermal crystallization technology, applied in the direction of crystalline aluminosilicate zeolite, can solve the problems of high production cost of titanium-silicon molecular sieve, cumbersome preparation method, low content of framework titanium, etc. The generation and preparation methods are simple, and the effect of increasing the content
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Embodiment 1
[0032] At 25°C, first mix tetrapropylammonium bromide, tetraethyl orthosilicate, and water to form A; mix the pore expander with water to form B; add emulsifier TX-10 to butyl titanate to form emulsion C; Pass inert gas into the emulsion C and use the shock generated by the bubble burst to demulsify the emulsion to release the titanium source; then mix A and B and drop them into C to form D, and use tetramethyl hydroxide during the dropwise addition Adjust the pH value with ammonium to make the pH value = 12. After the titration is completed, place D in a stainless steel crystallization reaction kettle for crystallization at 170°C for 48 hours, filter and wash the resulting crystallized product, and dry 6 pieces at 120°C. Hours, calcined at 550°C for 6 hours to obtain a large-diameter TS-1 molecular sieve. Among them, tetraethyl orthosilicate: emulsifier (TX-10): butyl titanate: tetrapropylammonium bromide: pore expander (hexamethyleneimine): the molar ratio of water is 1:0.06...
Embodiment 2
[0034] At 25°C, tetrapropylammonium bromide, tetraethyl orthosilicate, and water are first mixed to form A; the pore expander is mixed with water to form B; the emulsifier acetylacetone is added to butyl titanate to form emulsion C; The inert gas is introduced into the emulsion C, and the shock generated by the bursting of the bubbles is used to demulsify the emulsion to release the titanium source; then A and B are mixed and dropped into C to form D, and tetramethyl hydroxide is used during the dropwise addition process. Adjust the pH value with ammonium to make the pH value = 12. After the titration is completed, place D in a stainless steel crystallization reaction kettle for crystallization at 170°C for 60 hours, filter and wash the resulting crystallized product, and dry 5 pieces at 120°C. Hours, calcined at 550°C for 5 hours to obtain a large-diameter TS-1 molecular sieve. Among them, ethyl orthosilicate: emulsifier acetylacetone: butyl titanate: tetrapropylammonium brom...
Embodiment 3
[0036] At 25°C, first mix tetrapropylammonium bromide, propyl orthosilicate, and water to form A; mix the pore expander with water to form B; add emulsifier TX-10 to butyl titanate to form emulsion C; Pass inert gas into the emulsion C and use the shock generated by the bursting of the bubbles to break the emulsion to release the titanium source; then mix A and B and drop them into C to form D, and use tetramethyl hydrogen in the process of dropping Adjust the pH value with ammonium oxide to make the pH value = 12. After the titration is completed, place D in a stainless steel crystallization reactor and crystallize at 170°C for 60 hours. Filter and wash the obtained crystallized product, and dry it at 120°C for 60 hours. hour, and roasted at 550°C for 6 hours to obtain a large-diameter TS-1 molecular sieve. Among them, propyl orthosilicate: emulsifier TX-10: butyl titanate: tetrapropylammonium bromide: pore expander (trimethylbenzene): the molar ratio of water is 1:0.06:0.06:...
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