A kind of production method for preparing ammonium phosphate by-product longan special fertilizer

A production method and technology of ammonium phosphate, which are applied in the directions of phosphate, phosphorus oxyacid, application, etc., can solve the problems of increasing the preparation cost of ammonium phosphate products, affecting the purity of ammonium phosphate products, and low purity of ammonium phosphate products, and achieving remarkable results. Environmental value and economic benefits, improved land utilization, improved yield and quality

Inactive Publication Date: 2016-07-06
GUIZHOU UNIV +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the preparation of this special fertilizer for longan is based on the demand for longan, the complexing agent formed cannot make the nitrogen, phosphorus, and potassium elements form a compound fertilizer structure in a compound state, so that the crops can regenerate. When absorbing one or two elements in nitrogen, phosphorus and potassium, other elements will remain in the soil, and then biochemically react with the soil, causing damage to the soil structure layer, and causing environmental pollution
[0004] At the same time, in the preparation process of ammonium phosphate products, one of wet-process phosphoric acid and hot-process phosphoric acid is usually used to prepare ammonium phosphate products. This process will affect the purity of ammonium phosphate products, making ammonium phosphate The purity of the product is low. Therefore, it is necessary to design an additional purification process for ammonium phosphate to purify the ammonium phosphate product, thereby increasing the preparation cost of the ammonium phosphate product. Therefore, some people react by using phosphoric acid and urea at a temperature lower than 80 degrees Celsius. To produce an intermediate such as urea phosphate, and then use the intermediate as a raw material to react with ammonia gas to produce ammonium phosphate products. This process requires cooling and cyclic crystallization of ammonium phosphate products, but often requires deep crystallization of ammonium phosphate products. Only in this way can a large amount of nitrogen and phosphorus nutrients in the waste liquid be discharged into the environment, thereby avoiding the waste of resources and reducing the production cost of ammonium phosphate products. However, due to the deep crystallization process, other products will also be crystallized out. , thereby affecting the purity of the ammonium phosphate product

Method used

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  • A kind of production method for preparing ammonium phosphate by-product longan special fertilizer
  • A kind of production method for preparing ammonium phosphate by-product longan special fertilizer
  • A kind of production method for preparing ammonium phosphate by-product longan special fertilizer

Examples

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Embodiment 1

[0043] A production method for preparing ammonium phosphate by-product longan special fertilizer, using phosphoric acid and urea to mix at a molar ratio of 1.1:1, stirring and reacting at a temperature of 93°C for 1 hour to obtain an intermediate slurry; Ammonia gas was introduced, and the reaction temperature was controlled to be 70°C. After stirring and reacting for 23 minutes, the pH value of the end point was controlled to be 9.8 to obtain ammonium phosphate slurry; And the nitrogen and phosphorus elements in the solution are detected, analyzed and adjusted so that the molar ratio of the nitrogen and phosphorus elements in the solution is 1.1:1.6, stop crystallization and filter, the filter cake is an ammonium phosphate product, and potassium and phosphorus are added to the filtrate. Medium and trace element compounds, and adjust the molar ratio of nitrogen, phosphorus and potassium elements in the solution to 1.3:1.7:1.1 to obtain the first product of the compound fertiliz...

Embodiment 2

[0051] A production method for preparing ammonium phosphate by-product longan special fertilizer, using phosphoric acid and urea to mix at a molar ratio of 2.4:1, stirring and reacting for 2 hours at a temperature of 113°C to obtain an intermediate slurry; Ammonia gas was introduced, and the reaction temperature was controlled to be 80°C. After stirring and reacting for 33 minutes, the pH value of the end point was controlled to be 11.4 to obtain ammonium phosphate slurry; And the nitrogen and phosphorus elements in the solution are detected, analyzed and adjusted so that after the molar ratio of the nitrogen and phosphorus elements in the solution is 1.1:2.1, the crystallization is stopped and the filtration process is carried out. The filter cake is an ammonium phosphate product, and potassium components and Medium and trace element compounds, and adjust the molar ratio of nitrogen, phosphorus and potassium elements in the solution to 1.3:2.3:1.3 to obtain the first product o...

Embodiment 3

[0059] A production method for preparing ammonium phosphate by-product longan special fertilizer, using phosphoric acid and urea to mix at a molar ratio of 1.7:1, stirring and reacting at a temperature of 98°C for 1.5 hours to obtain an intermediate slurry; Ammonia gas was passed into the medium, and the reaction temperature was controlled at 75°C. After stirring for 28 minutes, the pH value of the end point was controlled to be 10.5 to obtain ammonium phosphate slurry; then the ammonium phosphate slurry was placed in a circulating cooling crystallizer for circulating cooling crystallization treatment , and detect, analyze and adjust the nitrogen and phosphorus elements in the solution so that the molar ratio of the nitrogen and phosphorus elements in the solution is 1.1:1.9, stop crystallization and filter, the filter cake is an ammonium phosphate product, and add potassium to the filtrate and medium and trace element compounds, and adjust the molar ratio of nitrogen, phosphor...

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Abstract

The invention relates to the technical field of chemical industry, and especially relates to a method for preparing ammonium phosphate and preparing a special fertilizer for longan as a byproduct. The nutrition demand condition in the longan growth process is analyzed, and the disadvantages of an ammonium phosphate product preparation technology are analyzed, so the method combining a technology for preparing a special combined composite fertilizer for longan with a technology for preparing the ammonium phosphate product makes the two technologies complement to each other, reduces the discharge amount of a waste liquid in the ammonium phosphate product preparation technology, avoids the disadvantages of low purity of the ammonium phosphate product due to deep crystallization and improves the quality of the ammonium phosphate product. The adjustment and the matching of nutritional elements in the waste liquid make the prepared special composite fertilizer for longan meet nutrition demands of longan, so the growth speed of longan is improved, the output and the quality of longan are improved, the hardening rate of soil is reduced, the utilization rate of soil is improved, and the method has substantial environmental protection values and substantial economic benefits.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a production method for preparing ammonium phosphate by-product longan special fertilizer. Background technique [0002] Longan is a perennial evergreen fruit tree. After planting, the root system continuously and selectively absorbs certain nutrients from the soil for a long time, which is likely to cause a deficiency of certain nutrients, which requires continuous supplementation in production. According to analysis, an orchard with a yield of 1,000 kg of fresh longan fruit per mu needs to absorb 4.01-4.8 kg of nitrogen, 1.46-1.58 kg of phosphorus, and 7.54-8.96 kg of potassium from the soil every year. The ratio of nitrogen, phosphorus, and potassium is 10:3:17 -20. [0003] Usually, crops have a low absorption rate of nitrogen, phosphorus and potassium in fertilized nitrogen, phosphorus and potassium fertilizers, and most of the nitrogen, phosphorus and potassium e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B25/28C05G1/06
Inventor 陈肖虎廖吉星高贵龙张文李军旗郑培俊薛涛
Owner GUIZHOU UNIV
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