A polymer water-based coating that responds to ultraviolet light
A water-based coating, responsive technology, applied in polyester coatings, polyurea/polyurethane coatings, coatings, etc., can solve problems such as single function, and achieve the effect of easy observation, easy preparation, and easy coating
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Embodiment 1
[0043] The aqueous dispersion of nanopolymer particles containing spiropyran photochromic molecular groups described in this example is synthesized by a miniemulsion polymerization process, including the following steps:
[0044] 1) Prepare water phase: mix emulsifier, pH buffer solution and water, described emulsifier is sodium dodecylsulfonate, described pH buffer agent is sodium bicarbonate; Wherein sodium lauryl sulfate content 20mmol / L, sodium bicarbonate content 10mmol / L; the rest is water;
[0045] 2) Prepare the oil phase: mix the monomer, crosslinking agent and co-stabilizer, the monomer is selected from 0.1 part of N-hydroxyethylspiropyranyl methacrylate and 2 parts of methyl methacrylate, the resulting The crosslinking agent is selected from 0.1 part of 1,4-butanediol diacrylate, and the co-stabilizer is 0.05 part of polystyrene with a weight average molecular weight of 5000;
[0046] 3) Mixing and emulsification: the water phase and the oil phase are mixed and em...
Embodiment 2
[0051]Only change the commercially available Dulux white polyacrylate interior wall latex paint into Dulux white polyacrylate exterior wall white latex paint in step 2) of embodiment 1, and the rest are identical to embodiment 1.
[0052] Apply the polymer water-based paint prepared above to pure wood pulp thick paper by heat-sealing, and form a film after drying, put it in a transparent plastic bag and hang it at the place where the ultraviolet disinfection lamp is exposed. After a few minutes, the color changes from colorless or Very light purple to dark blue-purple. The color returns to its original light state after hours of exposure to white light.
Embodiment 3
[0054] Only change the cross-linking agent in step 1) of Example 1 into 0.2 part of divinylbenzene, and the rest are identical to Example 1.
[0055] Apply the polymer water-based paint prepared above to pure wood pulp thick paper by heat-sealing, and form a film after drying, put it in a transparent plastic bag and hang it at the place where the ultraviolet disinfection lamp is exposed. After a few minutes, the color changes from colorless or Very light purple to dark blue-purple. The color returns to its original light state after hours of exposure to white light.
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