Epoxy modified polyurethane double-component grouting material for road engineering maintenance and preparation method thereof
A technology of epoxy modification and grouting material, applied in the field of epoxy modified polyurethane two-component grouting material and its preparation, can solve problems such as reducing the use of amine catalysts, achieve good compatibility, avoid hysteresis, Mild and efficient reaction conditions
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Embodiment 1
[0031]
[0032] The preparation method comprises the following steps:
[0033] Using diethanolamine and epoxy resin CYD-128 as raw materials, the molar ratio of diethanolamine:epoxy resin CYD-128 is 2:1, using methyl ethyl ketone as solvent, the reaction temperature is 80°C, and the reaction time is 4 hours. Epoxy resin CYD128-DEA adduct solution; distill the reaction product to remove the solvent under reduced pressure; add polyether YC-4110, foaming agent water, foam stabilizer SD-601 and catalyst dibutyltin dilaurate, stir and mix evenly After natural cooling to room temperature, the A component of the grouting material can be obtained; polyphenyl polymethylene polyisocyanate (PAPI) is used as the B component; the A and B components are mixed and stirred evenly, and the epoxy resin can be obtained. Modified polyurethane grouting material.
[0034] The volume began to expand after 30s, and the gel solidified after 90s; the mechanical properties test results showed that t...
Embodiment 2
[0037]
[0038] The preparation method comprises the following steps:
[0039] Using diethanolamine and epoxy resin CYD-128 as raw materials, the molar ratio of diethanolamine:epoxy resin CYD-128 is 1:1, using methyl ethyl ketone as solvent, the reaction temperature is 80°C, and the reaction time is 4 hours. The solution of the epoxy resin CYD128-DEA adduct; the reaction product is distilled off under reduced pressure to remove the solvent; add a certain amount of polyether YC-4110, foaming agent water, foam stabilizer SD-601 and catalyst dibutyltin dilaurate, After stirring and mixing evenly, cool naturally to room temperature to get component A of the grouting material; polyphenyl polymethylene polyisocyanate (PAPI) is used as component B; components A and B are mixed and stirred evenly according to the above ratio, The epoxy-modified polyurethane grouting material can be obtained.
[0040] The volume began to expand after 40s, and the gel solidified after 100s; the mechan...
Embodiment 3
[0043]
[0044] The preparation method comprises the following steps:
[0045] Using diethanolamine and epoxy resin CYD-128 as raw materials, the molar ratio of diethanolamine:epoxy resin CYD-128 is 1.5:1, using methyl ethyl ketone as solvent, the reaction temperature is 80°C, and the reaction time is 3 hours. The solution of the epoxy resin CYD128-DEA adduct; the reaction product is distilled off under reduced pressure to remove the solvent; add a certain amount of polyether YC-4110, foaming agent water, foam stabilizer SD-601 and catalyst dibutyltin dilaurate, After stirring and mixing evenly, cool naturally to room temperature to get component A of the grouting material; polyphenyl polymethylene polyisocyanate (PAPI) is used as component B; components A and B are mixed and stirred evenly according to the above ratio, The epoxy-modified polyurethane grouting material can be obtained.
[0046] The volume began to expand after 50s, and the gel solidified after 120s; the me...
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