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A kind of environment-friendly asphalt and preparation method thereof

An environmentally friendly and asphalt technology, applied in the processing of tar asphalt/petroleum asphalt/natural asphalt, chemically processing tar asphalt/petroleum asphalt/natural asphalt, petroleum industry, etc. and other problems, to achieve the effects of low cost, increased β resin content, and increased coking value

Active Publication Date: 2018-07-06
SINOSTEEL ANSHAN RES INST OF THERMO ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process includes adding alkali substances to the reaction kettle to adjust the pH value, which undoubtedly increases the salt and alkali substances in the prepared asphalt, which is difficult to remove, increases the ash content of the asphalt, and affects its performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0025] The preparation method of an environment-friendly asphalt according to the present invention comprises the following steps: weighing 100 parts by weight of raw materials, adding 1 to 20 parts by weight of modifier and 1 to 20 parts by weight of accelerator, mixing and stirring evenly, Under gas protection, raise the temperature to 120-350°C, and polymerize at constant temperature for 1-20 hours; stop nitrogen or argon, and distill under the pressure of 0-30kPa to obtain environmentally friendly asphalt.

[0026] The purpose of distillation under the pressure of 0-30kPa is to recover the accelerator.

[0027] The softening point of the prepared environment-friendly bitumen is 20-300 DEG C, and the content of benzo[a]pyrene is lower than 500ppm. Benzo[a]pyrene (BaP) content determination method can adopt high performance liquid chromatography (HPLC).

Embodiment 1

[0030] 100 parts by weight of soft asphalt with a softening point of 44°C and QI (quinoline insolubles) of 1.45% are placed in the reactor, heated to 100-120°C to melt, and 5 parts by weight of paraformaldehyde and 3 parts by weight of benzenesulfonic acid (boiling point 137°C, normal pressure), mix and stir evenly, heat up to 130°C under nitrogen protection, and polymerize at constant temperature for 5 hours; stop nitrogen, heat up to 160°C, and distill under reduced pressure under 1kPa pressure 15min, get the environment-friendly asphalt product.

[0031] The analysis and detection indicators of this environmentally friendly asphalt product are as follows: softening point 93°C, toluene insoluble content of 35.80%, quinoline insoluble content of 4.55%, β resin content of 31.25%, coking value of 58.08%, benzo[a]pyrene (BaP) content was 463.1 ppm.

Embodiment 2

[0033] Put 100 parts by weight of medium-temperature pitch with a softening point of 85°C and a QI of 4.88% in the reactor, heat it up to 100-120°C to melt it, and then slowly add 10 parts by weight of terephthalaldehyde and 5 parts by weight of formaldehyde Base sulfonic acid (boiling point 167°C, 13.33KPa), mix and stir evenly, heat up to 170°C under nitrogen protection, and polymerize at constant temperature for 4 hours; stop nitrogen, heat up to 200°C, and distill under reduced pressure at 1kPa for 15min to obtain environmental protection Bituminous products.

[0034] The analysis and detection indicators of this environmentally friendly asphalt product are as follows: softening point 122°C, toluene insoluble content 40.87%, quinoline insoluble content 6.62%, β resin content 34.25%, coking value 61.88%, BaP content 335.2ppm.

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Abstract

The invention relates to an environmentally friendly asphalt, which comprises the following components: 100 parts by weight of raw materials, 1-20 parts by weight of modifier, and 1-20 parts by weight of accelerator. The raw materials are selected from aromatic heavy oil, coal tar pitch and modified One or two or more of asphalt. The preparation method is as follows: add modifier and accelerator to the raw material, mix and stir evenly, heat up to 120-350°C under the protection of nitrogen or argon, and polymerize at constant temperature for 1-20 hours; stop nitrogen or argon, at 0 ~30kPa pressure distillation, that is, the production of environmentally friendly asphalt. Compared with the prior art, the beneficial effect of the present invention is that the content of carcinogenic polycyclic aromatic hydrocarbons in raw materials is greatly reduced, there is no modifier and accelerator residue, and the accelerator can be recycled, and the produced environmentally friendly asphalt The benzo[a]pyrene (BaP) content is lower than 500ppm, which is of great significance to human health and environmental pollution control; the preparation method has simple and easy process, mild reaction conditions, favorable energy saving and consumption reduction, low cost and effective quick.

Description

technical field [0001] The invention relates to the technical field of coal tar pitch deep processing, in particular to an environment-friendly pitch and a preparation method thereof. Background technique [0002] Coal tar pitch is the residue of coal tar distillation and extraction fractions (light oil, phenol oil, naphthalene oil, washing oil and anthracene oil, etc.), and is a thermoplastic material with unique strong bonding ability, rich carbon and low ash, and Solid carbonaceous materials have excellent compatibility and affinity, high coking residual carbon value, easy graphitization of carbonized products, good penetration and wettability, cheap and easy to obtain, and are widely used in aluminum smelting, steel smelting, carbon Industry, refractory materials, building materials and road construction and other industries. Coal tar pitch contains many carcinogenic polycyclic aromatic hydrocarbons, especially the strong carcinogen benzo[a]pyrene, which seriously endan...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10C3/02
CPCC10C3/026
Inventor 孟庆波何莹屈滨刘书林武全宇陈雪杨桦张功多
Owner SINOSTEEL ANSHAN RES INST OF THERMO ENERGY CO LTD
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