A kind of environment-friendly asphalt and preparation method thereof
An environmentally friendly and asphalt technology, applied in the processing of tar asphalt/petroleum asphalt/natural asphalt, chemically processing tar asphalt/petroleum asphalt/natural asphalt, petroleum industry, etc. and other problems, to achieve the effects of low cost, increased β resin content, and increased coking value
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[0025] The preparation method of an environment-friendly asphalt according to the present invention comprises the following steps: weighing 100 parts by weight of raw materials, adding 1 to 20 parts by weight of modifier and 1 to 20 parts by weight of accelerator, mixing and stirring evenly, Under gas protection, raise the temperature to 120-350°C, and polymerize at constant temperature for 1-20 hours; stop nitrogen or argon, and distill under the pressure of 0-30kPa to obtain environmentally friendly asphalt.
[0026] The purpose of distillation under the pressure of 0-30kPa is to recover the accelerator.
[0027] The softening point of the prepared environment-friendly bitumen is 20-300 DEG C, and the content of benzo[a]pyrene is lower than 500ppm. Benzo[a]pyrene (BaP) content determination method can adopt high performance liquid chromatography (HPLC).
Embodiment 1
[0030] 100 parts by weight of soft asphalt with a softening point of 44°C and QI (quinoline insolubles) of 1.45% are placed in the reactor, heated to 100-120°C to melt, and 5 parts by weight of paraformaldehyde and 3 parts by weight of benzenesulfonic acid (boiling point 137°C, normal pressure), mix and stir evenly, heat up to 130°C under nitrogen protection, and polymerize at constant temperature for 5 hours; stop nitrogen, heat up to 160°C, and distill under reduced pressure under 1kPa pressure 15min, get the environment-friendly asphalt product.
[0031] The analysis and detection indicators of this environmentally friendly asphalt product are as follows: softening point 93°C, toluene insoluble content of 35.80%, quinoline insoluble content of 4.55%, β resin content of 31.25%, coking value of 58.08%, benzo[a]pyrene (BaP) content was 463.1 ppm.
Embodiment 2
[0033] Put 100 parts by weight of medium-temperature pitch with a softening point of 85°C and a QI of 4.88% in the reactor, heat it up to 100-120°C to melt it, and then slowly add 10 parts by weight of terephthalaldehyde and 5 parts by weight of formaldehyde Base sulfonic acid (boiling point 167°C, 13.33KPa), mix and stir evenly, heat up to 170°C under nitrogen protection, and polymerize at constant temperature for 4 hours; stop nitrogen, heat up to 200°C, and distill under reduced pressure at 1kPa for 15min to obtain environmental protection Bituminous products.
[0034] The analysis and detection indicators of this environmentally friendly asphalt product are as follows: softening point 122°C, toluene insoluble content 40.87%, quinoline insoluble content 6.62%, β resin content 34.25%, coking value 61.88%, BaP content 335.2ppm.
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