Method of diesel oil oxidation extraction and desulfurization
A diesel oil extraction technology, applied in the field of diesel oxidation extraction desulfurization, can solve the problems of high processing cost, difficulty in removing thiophene sulfides, large investment, etc., to reduce operating costs, prevent oil quality from being affected, and reduce production costs Effect
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Embodiment 1
[0038] Embodiment 1: the preparation of catalyst
[0039] The expression of the phase transfer catalyst of the present invention is Q 3 [XM n o q ], where: 1≤n≤11;
[0040] Q is a quaternary ammonium salt cation (C x h 2x+1 ) 4 N + ), the carbon chain length of at least one group in the quaternary ammonium salt cation is greater than or equal to 8 carbon atoms. It is not difficult to understand that the quaternary ammonium salt ion in the phase transfer catalyst of the present invention can be one of the following:
[0041] (C 8 h 17 ) 4 N + , (C 12 h 25 ) 4 N + , (C 16 h 33 ) 4 N + , (π-C 5 h 5 N + C 16 h 33 ), [(C 18 h 37 )(75%)+(C 16 h 33 )(25%)] 2 N + (CH 3 ) 2 , (C 18 h 37 ) 2 N + (CH 3 ) 2 .
[0042] X is phosphorus, silicon or arsenic, preferably phosphorus or arsenic is selected for effect, and phosphorus is the best effect.
[0043] M is molybdenum or tungsten, the most effective is tungsten.
[0044] It should be noted that as...
Embodiment 2
[0047] (1) Take 25ml of hydrogenated refined diesel oil with a sulfur content of 340ppm in a conical flask, add 0.02248g of catalyst A (after grinding) at room temperature, then add 0.11ml of hydrogen peroxide, stir vigorously for 30min, (2) put the above treatment Catalyst is recovered by centrifugal separation of diesel oil. (3) Add 13ml of 5% sodium thiosulfate solution to the diesel oil treated in the above step (2), stir for 30min, remove the lower aqueous solution with a separatory funnel, wash with water three times (25ml each time), and use 10g of water and sodium sulfate to dry. (4) Extract the dry diesel oil with 25ml of composite extractant ([N-methylpyrrolidone: (N-methylpyrrolidone+water)]=75-95%), separate the lower composite extractant, and repeat the extraction twice. The sulfur content of the obtained diesel oil was determined by microcoulomb titration, and the results are listed in Table 1.
Embodiment 3
[0049] The temperature of step 1 is 30 ℃, all the other operating conditions are the same as embodiment 2.
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