A kind of organic compound containing dimethyl anthracene and its application
An organic compound, dimethyl anthracene technology, applied in the field of organic optoelectronic materials, can solve problems such as disparity, and achieve the effects of avoiding aggregation, reducing efficiency roll-off and distribution balance
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Embodiment 1
[0057] Embodiment 1: the synthesis of intermediate A1:
[0058] synthetic route:
[0059]
[0060]
[0061] Add 11.8g of 1,4-dibromobenzene (0.05mol) and 1.33g of Mg powder (0.055mol) and 60ml of tetrahydrofuran to a 250ml four-necked flask under nitrogen atmosphere, heat and reflux for 4 hours, the reaction is complete, and the format Reagent;
[0062] Dissolve 11.1g of 10,10-dimethylanthrone (0.05mol) in 50ml of tetrahydrofuran, add the above-mentioned Grignard reagent dropwise, react at 60°C for 24 hours, a large amount of white precipitate is formed, and finally add saturated NHCl 4 Convert Grignard salt into alcohol; after the reaction, extract with ether, dry and rotary evaporate, petroleum ether: dichloromethane mixed solvent (3:2) silica gel column purification to obtain a slightly yellow solid tertiary alcohol (yield 88%) ; using DEI-MS to identify the compound, formula C 22 h 19 BrO, detection value [M+1] + = 379.03, calculated value 378.06;
[0063] Take...
Embodiment 2
[0064] Embodiment 2: the synthesis of intermediate A2:
[0065] synthetic route:
[0066]
[0067] Intermediate A2 was prepared according to the synthetic method of intermediate A1 in Example 1, the difference being that the compound bromobenzene was replaced by 1,1'-biphenyl;
[0068] Using DEI-MS to identify the compound, formula C 34 h 27 Br, detection value [M+1] + =514.85, calculated value 514.13.
Embodiment 3
[0069] Embodiment 3: the synthesis of intermediate A3:
[0070] synthetic route:
[0071]
[0072] Prepare intermediate A3 by the synthetic method of intermediate A1 among the embodiment 1, difference is to replace bromobenzene with benzene in the third step reaction;
[0073] Using DEI-MS to identify the compound, formula C 28 h 23 Br, detection value [M+1] + =438.10, calculated value 438.87.
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